The RPOC-NCR is composed of the following members:
| Local Chief Executive | Local Government Unit | |
| 1 | Hon. Dale Gonzalo R. Malapitan | City of Caloocan |
| 2 | Hon. Imelda T. Aguilar | City of Las Piñas |
| 3 | Hon. Mar-Len Abigail S. Binay | City of Makati |
| 4 | Hon. Jeannie N. Sandoval | City of Malabon |
| 5 | Hon. Benjamin S. Abalos Sr. | City of Mandaluyong |
| 6 | Hon. Maria Sheila H. Lacuna-Pangan | City of Manila |
| 7 | Hon. Marcelino R. Teodoro | City of Marikina |
| 8 | Hon. Rozzano Rufino B. Biazon | City of Muntinlupa |
| 9 | Hon. John Reynald M. Tiangco | City of Navotas |
| 10 | Hon. Eric L. Olivarez | City of Parañaque |
| 11 | Hon. Imelda Calixto-Rubiano | Pasay City |
| 12 | Hon. Victor Ma. Regis N. Sotto | City of Pasig |
| 13 | Hon. Miguel F. Ponce III | Municipality of Pateros |
| 14 | Hon. Ma. Josefina G. Belmonte | Quezon City |
| 15 | Hon. Francisco Javier M. Zamora | City of San Juan |
| 16 | Hon. Maria Laarni L. Cayetano | City of Taguig |
| 17 | Hon. Weslie T. Gatchalian | City of Valenzuela |
| Head of Agency | Agencies | |
| 18 | PMGen Edgar Alan O Okubo | NCRPO |
| 19 | BGen Alexei C Musñgi | AFP JTF NCR |
| 20 | Dir. Maria Lourdes L. Agustin, CESO III | DILG NCR |
| 21 | FCSupt Nahum B Tarroza | BFP NCR |
| 22 | Dir. Emerson R Rosales | PDEA NCR |
| 23 | Atty. Romando S. Artes | MMDA |
| 24 | Secretary Catalino S. Cuy | DDB |
| 25 | Undersecretary Mark Steven Pastor | DOTr - Road Transport and Infrastructure |
| 26 | Prosecutor General Benedicto Malcontento | DOJ |
| 27 | Atty. Norman G. Tansingco | BI |
| 28 | Dir. Dennis Godfrey F. Gammad | NICA-NCR |
| 29 | ARD Ferdinand Quirante | NAPOLCOM-NCR |
| 30 | JCSupt Efren A Nemeño, DPA, TLPE | BJMP-NCR |
| 31 | CG RADM Hostillo Arturo E Cornelio | PCG-NCR |
| 32 | PCol Boots M Aseo | PNP-MG RMU |
| 33 | PLTCOL Joel D Casupanan | HPG-NCR STU |
| 34 | Atty. Zona Russet M. Tamayo | LTFRB-NCR |
| 35 | Dir. Roque l. Verzosa lll | LTO-NCR West |
| 36 | Dir. Rommel J. Vallejo, CPA | NBI-NCR |
| 37 | Dir. Romulo M. Cabantac | OCD-NCR |
| 38 | Atty. Kristian Jeff C. Episcope | CHR-NCR |
| 39 | Dir. Aleli Annie Grace P. Sudiacal, MD, MPH, CESE | DOH-MMCHD |
| 40 | Atty. Michael Joseph J. Lorico | DSWD-NCR |
| 41 | Dir. Wilfredo E. Cabral | DepEd-NCR |
| 42 | Dir. Julieta M. Paras | CHED-NCR |
| 43 | Dir. Jovencio M. Ferrer, Jr | TESDA-NCR |
| 44 | Dir. Jacqueline A. Caancan, CESO III | DENR-NCR |
| 45 | Dir. Lorna M. Malaluan, CESO IV | DPWH-NCR |
| 46 | Dir. Marcelina Alcantara | DTI-NCR |
| 47 | Dir. Ruby P. Muro | DBM-NCR |
| 48 | Dir. Emver P. Cortez | PIA-NCR |
| 49 | Dir. Sharlene Zabala-Batin | DOT-NCR |
| 50 | Dir. Dimapuno A. Datu-Ramos, Jr., CESO III | NCMF NCR |
| 52 | Commissioner Bienvenido Y. Rubio | BoC |
| 52 | Hon. Ziffred A. Ancheta | LnB-NCR |